Electron Relaxation and Molecular Vibrations: Triatomic Systems of the First‐Row Elements, the Methyl Radical, and Diazomethane and Ketene

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Electron Relaxation and Molecular Vibrations: Triatomic Systems of the First-Row Elements, the Methyl Radical, and Diazomethane and Ketene

The well-known second-order perturbation method is used to correlate the bond-bond interaction constants in ground and excited electronic states of triatomic systems of the first-row elements, and unusual force constants in diazomethane and ketene with the effect of electron relaxation. The thirdand fourthorder perturbation schemes are used to determine qualitatively the contributions to the th...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 1970

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.1673427